'What's My Name?' - a collaboration with rapper Drake - marks the second cut from her Loud album, and will be released on January 10.
Discussing the track - which has already topped the charts in the US - producer L.A Reid said in a press release: "Rihanna is a true original, a gifted hitmaker, with a style and a musical flair of her own.
"We really honed in the songs and expressions that would bring out the best in her already incredible gift. I am especially proud of this project, as I feel it perhaps best captures her spirit and essence of Rihanna."
Loud is on course to take second place on this Sunday's album chart, with predicted sales of 70,000.
